High temperature oxidation of powder metallurgy
two-phase Cu-Cr alloys under low oxygen pressure①
two-phase Cu-Cr alloys under low oxygen pressure①
(1. State Key Laboratoryfor Corrosion and Protection, Institute of Corrosion and Protection of Metals,
Chinese Academy of Sciences, Shenyang110015, P.R.China;
2. Department of Chemical Machinery,
Shenyang Institute of Chemical Technology, Shenyang110021, P.R.China)
Chinese Academy of Sciences, Shenyang110015, P.R.China;
2. Department of Chemical Machinery,
Shenyang Institute of Chemical Technology, Shenyang110021, P.R.China)
Abstract: The oxidation of two-phase Cu-Cr alloys containing 25% and 50% Cr prepared by powder metallurgy (PM) with a rather uniform two-phase microstructure has been studied at 700~900℃under oxygen pressure below the stability of the copper oxides. The two PM alloys oxidized very slowly and formed only external Cr2O3scales rather than undergoing an internal oxidation of chromium. This result is attributed mainly to a supply of chromium from the small Cr-rich particles dispersed within the Cu-rich phase. The oxidation kinetics of the two PM Cu-Cr alloys approximately followed the parabolic rate law. The scaling rates are of the same order as those measured for pure chromium under the same oxygen pressure, but smaller than those for the alloys of similar composition prepared by normal arc melting techniques, whose compositions were largely non-uniform. The results are interpreted in terms of the two-phase nature of these alloys.
Key words: two-phase Cu-Cr alloys; oxidation; low oxygen pressure